Singer sweeps in at the last minute to claim top spot with her new Bond theme, 'Skyfall'
Leaked song to get official airing tonight
'I can't wait for everyone to hear it' he adds
CDs in Primark, Smith reunion and more top news
Track leaks ahead of official Friday premiere
Former Guns 'n' Roses man also praises Amy Winehouse
Star teams up with 77-piece orchestra for first new track since release of 21 album
Movie soundtrack recorded by 'Rolling In The Deep' star
Leaked image shows star's new single as excitement builds for next Bond theme
Celebrity website publishes extract from new tune
Star happy to stand still and belt out ballads
Carey Mulligan, Gwyneth Paltrow and Chris Martin also attend London iTunes show
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